Ni3S2/Ni(OH)2三维纳米片的制备及全解水性能研究

赵静, 张丽丽

化工新型材料 ›› 2020, Vol. 48 ›› Issue (8) : 160 -164.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (8) : 160-164. DOI: 10.19817/j.cnki.issn 1006-3536.2020.08.035
科学研究

Ni3S2/Ni(OH)2三维纳米片的制备及全解水性能研究

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Preparation of Ni3S2/Ni(OH)2 3D nanosheet as efficient electrocatalyst for water splitting

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摘要

采用简单的水热法在泡沫镍上成功制备出Ni3S2/Ni(OH)2三维纳米片,该自支撑电极在碱性介质中(1mol/L KOH)表现出优异的氧析出反应(OER)和氢析出反应(HER)的催化活性,在电流密度10mA/cm2时的过电位分别为330mV和290mV。将该电极同时作为电解水的阴极和阳极催化剂时,其在碱性全解水过程中也表现出优异的催化性能,在10mA/cm2时的过电位为420mV,并且表现出优异的催化稳定性。

Abstract

A simple hydrothermal method was used to successfully prepare Ni3S2/Ni(OH)2 3D nanosheets on nickel foam.The self-supporting electrode showed excellent catalytic activity of OER and HER in alkaline medium (1mol/L KOH).The overpotential at current density of 10mA/cm2 was 330mV and 290mV,respectively.When the electrode was used as both a cathode and an anode catalyst for water splitting,it also showed excellent catalytic performance with an overpotential of 420mV at 10mA/cm2 and excellent catalytic stability.

关键词

纳米片 / 氧析出 / 氢析出 / 全解水

Key words

nanosheet / oxygen evolution reaction (OER) / hydrogen evolution reaction (HER) / water splitting

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赵静, 张丽丽. Ni3S2/Ni(OH)2三维纳米片的制备及全解水性能研究[J]. 化工新型材料, 2020, 48(8): 160-164 DOI:10.19817/j.cnki.issn 1006-3536.2020.08.035

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参考文献

[1] Walter M G,Warrenge L,Mckone J R,et al.Solar water splitting cells[J].Chemical Review,2010,110(11):6446-6473.
[2] Kudo A,Miseki Y.Heterogeneous photocatalyst materials for water splitting[J].Chemical Society Reviews,2009,38(1):253-278.
[3] Tang T,Jiang W J,Niu S,et al.Electronic and morphological dual modulation of cobalt carbonate hydroxides by Mn doping toward highly efficient and stable bifunctional electrocatalysts for overall water splitting[J].Journal of the American Chemical Society,2017,139(24):8320-8328.
[4] Hu E,Feng Y,Nai J,et al.Construction of hierarchical Ni-Co-P hollow nanobricks with oriented nanosheets for effcient overall water splitting[J].Energy & Environmental Science,2018,11(4):872-880.
[5] Wu R,Zhang J,Shi Y,et al.Metallic WO2-carbon mesoporous nanowires as highly efficient electrocatalysts for hydrogen evolution reaction[J].Journal of the American Chemical Society,2015,137(22):6983-6986.
[6] Han L,Dong S,Wang E.Transition-metal (Co,Ni,and Fe)-based electrocatalysts for the water oxidation reaction[J].Advanced Materials,2016,28(42):9266-9291.
[7] Du X,Yang Z,Li Y,et al.Controlled synthesis of Ni(OH)2/Ni3S2 hybrid nanosheet arrays as highly active and stable electrocatalysts for water splitting[J].Journal of Materials Chemistry A,2018,6(16):6938-6946.
[8] Feng L L,Yu G,Wu Y,et al.High-index faceted Ni3S2 nanosheet arrays as highly active and ultrastable electrocatalysts for water splitting[J].Journal of the American Chemical Society,2015,137(44):14023-14026.
[9] Zhu C,Wang A L,Xiao W,et al.In situ grown epitaxial heterojunction exhibits high-performance electrocatalytic water splitting[J].Advanced Materials,2018,30(13):1705516.
[10] Hou Z,Shu C,Long J.Honeycomb-like Ni3S2 supported on Ni foam as high performance free-standing cathode for lithium oxygen batteries[J].Electrochimica Acta,2018,290:657-665.
[11] Wang A L,Xu H,Li G R.NiCoFe layered triple hydroxides with porous structures as high-performance electrocataysts for overall water splitting[J].ACS Energy Letter,2016,1(2):445-453.
[12] Wan S,Qi J,Zhang W,et al.Hierarchical Co(OH)F superstructure built by low-dimensional substructures for electrocatalytic water oxidation[J].Advanced Materials,2017,29(28):1700286.
[13] Hu C,Zhang L,Zhao Z J,et al.Synergism of geometric construction and electronic regulation:3D Se-(NiCo)Sx/(OH)x nanosheets for highly efficient overall water splitting[J].Advanced Materials,2018,30(12):1705538.
[14] Zhu Y L,Zhou W,Chen Z G,et al.SrNb0.1Co0.7Fe0.2O3-δ perovskite as a next-generation electrocatalyst for oxygen evolution in alkaline solution[J].Angewandte Chemie International Edition,2015,54(13):3897-3901.

基金资助

伊犁师范大学2020年度校级科研项目(2020YSZD001)

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